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Merck
CN

702854

酞菁铜(II)

triple-sublimed grade, >99.95% trace metals basis

别名:

CuPc, 酞菁蓝, 颜料蓝 15

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关于此项目

经验公式（希尔记法）:
C32H16CuN8
化学文摘社编号:
147-14-8
分子量:
576.07
EC Number:
205-685-1
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
329762407
MDL number:
MFCD00010719
Colour Index Number:
74160
Beilstein/REAXYS Number:
4121848

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SMILES string

c1ccc2c(c1)C3=NC4=[N@@H]5C(=Nc6n7c(N=C8c9ccccc9C%10=[N@@H]8[Cu]57N3C2=N%10)c%11ccccc6%11)c%12ccccc4%12

InChI key

XCJYREBRNVKWGJ-UHFFFAOYSA-N

InChI

1S/C32H16N8.Cu/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2

assay

>99.95% trace metals basis

form

powder

quality

triple-sublimed grade

mp

350 °C

λmax

678 nm

fluorescence

λem 404 nm

orbital energy

HOMO 5.2 eV , LUMO 3.5 eV 

OLED device performance

ITO/CuPc/NPD/Alq3/C60/Mg:Ag

  • Color: green
  • Max. Luminance: 17200 Cd/m2
, ITO/CuPc/NPD/Alq3/LiF/Al
  • Color: red
  • Max. Luminance: 2000 Cd/m2
  • Turn-On Voltage: 7.5 V
, ITO/CuPc/NPD/CBP:Firpic (6%)/BAlq3/LiF/Al
  • Color: blue
  • Max. EQE: 4.5 %

OPV device performance

ITO/CuPc/PTCDA/In

  • Short-circuit current density (Jsc): 53.1 mA/cm2
  • Open-circuit voltage (Voc): 0.57 V
  • Fill Factor (FF): 0.61
  • Power Conversion Efficiency (PCE): 4.2 %
, ITO/PEDOT:PSS/CuPc/C60/BCP/Al
  • Short-circuit current density (Jsc): 18.8 mA/cm2
  • Open-circuit voltage (Voc): 0.58 V
  • Fill Factor (FF): 0.52
  • Power Conversion Efficiency (PCE): 3.6 %

Quality Level

100

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相关类别

存储类别

11 - Combustible Solids

wgk

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
0000051785
0000046474
MKBP2128V
02905KJ

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Jiannan Dong et al.
Langmuir : the ACS journal of surfaces and colloids, 26(10), 6995-7006 (2010-01-16)
The dispersion stability and the zeta potentials of nonspherical crystalline (beta-form) copper phthalocyanine (CuPc) particles of hydrodynamic diameter d(h) approximately = 90 nm were investigated at 25 degrees C in water and in aqueous solutions of NaNO(3). The electrolyte concentrations
Richard Murdey et al.
The Journal of chemical physics, 134(23), 234702-234702 (2011-06-28)
The current flowing through a thin film of copper phthalocyanine vacuum deposited on a single crystal sapphire [0001] surface was measured during film growth from 0 to 93 nm. The results, expressed as conductance vs. nominal film thickness, indicate three
Jaron G Van Dijken et al.
Molecules (Basel, Switzerland), 17(9), 10119-10130 (2012-08-28)
We investigate the evolution of copper phthalocyanine thin films as they are etched with argon plasma. Significant morphological changes occur as a result of the ion bombardment; a planar surface quickly becomes an array of nanopillars which are less than
Yu Li Huang et al.
Langmuir : the ACS journal of surfaces and colloids, 26(5), 3329-3334 (2010-02-24)
The self-assembly of the binary molecular system comprising copper(II) phthalocyanine (CuPc) and copper-hexadecafluoro-phthalocyanine (F(16)CuPc) on graphite has been investigated by in situ low-temperature scanning tunneling microscopy (LT-STM). The adsorption of this binary molecular system on graphite results in the formation
Kai Xiao et al.
Journal of the American Chemical Society, 135(9), 3680-3687 (2013-02-02)
The epitaxial growth and preferred molecular orientation of copper phthalocyanine (CuPc) molecules on graphene has been systematically investigated and compared with growth on Si substrates, demonstrating the role of surface-mediated interactions in determining molecular orientation. X-ray scattering and diffraction, scanning
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