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341169

Sigma-Aldrich

Zinc phthalocyanine

Dye content 97 %

Synonym(s):

Phthalocyanine zinc salt

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1047321000
¥418.39

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Estimated to ship on2025年4月27日Details

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1047321000
¥418.39

About This Item

Empirical Formula (Hill Notation):
C32H16N8Zn
CAS Number:
14320-04-8
Molecular Weight:
577.91
Beilstein:
4121852
EC Number:
238-262-5
MDL number:
MFCD00041955
UNSPSC Code:
12352103
PubChem Substance ID:
24860701
NACRES:
NA.23

¥418.39

List Price¥1,394.66Save 70%

Estimated to ship on2025年4月27日Details

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composition

Dye content, 97%

Quality Level

100

reaction suitability

reagent type: catalyst
core: zinc

λmax

701 nm

Orbital energy

HOMO 5.17 eV (CV)
LUMO 3.78 eV (CV)

OPV Device Performance

ITO/ZnPc:P60 (1:1)/Bphen/Ag

  • Short-circuit current density (Jsc): 11.7 mA/cm2
  • Open-circuit voltage (Voc): 0.54 V
  • Fill Factor (FF): 0.62
  • Power Conversion Efficiency (PCE): 3.9 %

SMILES string

[Zn]1n2c3nc4nc(nc5n1c(nc6nc(nc2c7ccccc37)c8ccccc68)c9ccccc59)c%10ccccc4%10

InChI

1S/C32H16N8.Zn/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2

InChI key

PODBBOVVOGJETB-UHFFFAOYSA-N

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Show Differences

1 of 4

This Item
106009107018103726
Methanol tested for EPA533 and EPA537.1 PFAS Methods LiChrosolv®

104732

Methanol

Methanol for analysis EMSURE® ACS,ISO,Reag. Ph Eur

106009

Methanol

Methanol for analysis EMPARTA® ACS

107018

Methanol

Methanol for UHPLC-MS LiChrosolv®

103726

Methanol

assay

≥99.9% (GC)

assay

≥99.9% (GC)

assay

≥99.8% (GC)

assay

99.9% (GC)

Quality Level

100

Quality Level

300

Quality Level

200

Quality Level

200

form

liquid

form

liquid

form

liquid

form

liquid

expl. lim.

36 %

expl. lim.

36 %

expl. lim.

36 %

expl. lim.

36 %

bp

64.7 °C (lit.)

bp

64.7 °C (lit.)

bp

64.7 °C (lit.)

bp

64.7 °C (lit.)

vapor pressure

410 mmHg ( 50 °C), 97.68 mmHg ( 20 °C)

vapor pressure

128 hPa ( 20 °C), 410 mmHg ( 50 °C), 97.68 mmHg ( 20 °C)

vapor pressure

128 hPa ( 20 °C), 410 mmHg ( 50 °C), 97.68 mmHg ( 20 °C)

vapor pressure

128 hPa ( 20 °C), 410 mmHg ( 50 °C), 97.68 mmHg ( 20 °C)

General description

Zinc (II) phthalocyanine (ZnPc) complexes show photosensitizing properties. Phthalocyanines show significant Π−Π interactions and easy formation of H aggregates.[1]

Application

Zinc phthalocyanine finds general applications in industry (catalysts, photoconductors etc) and biomedical (photodynamic therapy, PDT).[2] ZnPc may be used to photooxidise cyclohexane.[3] A study reports functionalization of polymer membrane with ZnPc.[4]

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves
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    Certificates of Analysis (COA)

    Lot/Batch Number
    0000267004
    0000267004
    SHBQ3573
    SHBP9359
    MKCN2418

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    Junseok Lee et al.
    Chemical communications (Cambridge, England), 49(15), 1545-1547 (2013-01-18)
    A photoresponsive drug releasing system based on mesoporous silica nanoparticles (MSN) was developed. A model drug was decorated on the surfaces via singlet oxygen sensitive linkers and a singlet oxygen-generating photosensitizer was loaded in the mesopores of the MSN. An
    Jiangtao Ren et al.
    Biosensors & bioelectronics, 35(1), 401-406 (2012-04-10)
    In this work, a simple and label-free fluorescent method via fluorescent indicator displacement (FID) was proposed for enantioselectively determining d-enantiomer of arginine vasopressin (DV) using DV-specific DNA aptamer (V-apt) and one guanidiniophthalocyanine dye (Zn-DIGP). Zn-DIGP that preferentially binds to single-stranded
    Zinc phthalocyanine photocatalyzed oxidation of cyclohexene.
    Sehlotho N and Nyokong T
    J. Mol. Catal. A: Chem., 219(2), 201-207 (2004)
    Sean Marrache et al.
    Integrative biology : quantitative biosciences from nano to macro, 5(1), 215-223 (2012-07-27)
    A therapeutic technology that combines the phototoxic and immune-stimulating ability of photodynamic therapy (PDT) with the widespread effectiveness of the immune system can be very promising to treat metastatic breast cancer. We speculated that the knowledge of molecular mechanisms of
    Anamika Ray et al.
    The journal of physical chemistry. B, 116(39), 11979-11998 (2012-08-23)
    The present article reports photophysical studies on supramolecular interaction of a zinc phthalocyanine derivative, namely, zinc-2,9,16,23-tetra-tert-butyl phthalocyanine (1) with C(60) and C(70) in solvents having varying polarity, i.e., toluene and 1,2-dichlorobenzene (DCB). The interesting feature of the present work is
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